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It'll be interesting to see what you do with Charlotte and family — I have a few little plans for them in my own TL.
I know the biggest change will be in that a-typical perfect Victorian family. Charlotte is young and differs from her Tory uncles, but in some aspects, she's really a lot like them. If anything, I still see a love for frivolity; the Regency period will die, but the Georgian period will not totally with it.
The British court will also be different. William IV was a pretty basic man, hated protocol, failed to follow the most basic courtly behaviors, and simplified how the royal palaces worke, firing the French chefs as well as George IV's German band that had cost some 18,000 pounds.
So, Charlotte will provide that typical Whiggish hope that many expected would sweep away the old Tory establishment, but I wonder if her monarchy will be a monarchy for the middle classes the way Victoria's was. For one thing, I remember Charlotte complained during her pregnancy that she hated being so fat. Botched medicine aside, I can see her totally hating family life, and unfortunately perpetuating the indirect childhood that she as well as her own father had been subjected too. Almost all the Hannoverian heirs hated their fathers... I just hope it isn't the case with Charlotte and hers.