Germany planned on a short war (because they believed they would lose a long one) so the lack of Haber-Bosch would make no difference. I would be surprised if any German planner considered it for a moment or was even aware of it beyond a 'reading the newspapers' level.
On point 2. Well the actual 'process' was developed in 1909 by Haber. BASF hired Bosch to industrialise it and that took a year. It then took 3 years to build the first industrial scale factory for it. Maybe you can squeeze some of those times, but it is still several years from having the idea to getting any useful production out of the factory and no crash programme can change that.
However Haber-Bosch was not the only way of fixing nitrogen, prior to that
Frank-Caro and
Birkeland-Eyde were used. They were more energy intensive which is why Haber-Bosch eventually took over. But it was eventually, Frank-Caro was used for decades and apparently dominated fertiliser production till after WW2. I suspect that Germany could muddle through without Haber-Bosch so they would not utterly run out of ammunition. But they will have far less nitrates and they will be more expensive to produce (in terms of resources as well as money) so the Germans will have to transfer resources from some other area. I suspect the German chemical weapons programme takes a hit and doesn't happen, because all the chemist and works have to work on nitrates (in OTL Haber got dragged into the chemical weapons programme for instance).
I think there would be no dramatic collapse, but a German army without chemical weapons, a poorer home front and with far less ammunition. I've seen it suggested artillery caused 60-70% of casualties in WW1, so a Germany without H-B just does not have the shells to inflict large casualties. Something like the OTL Verdun would be impossible for Germany, it might even turn into a French victory as the German artillery will run out of shells far earlier.
So at a first stab I'd say the Central Powers seek terms in early 1916, having finally run out of ammunition and a variety of desperate "last chance" offensives having failed.