The only problem with that is that the Kaiser had nothing to do with war planning. In fact, he was kept out specifically because the military wanted to have a free hand it what they considered 'their' realm. They heavily resented that the Kaiser would come in and give them orders to change things in the military, like with the machine gun issue. No branch, outside a few forward thinking individuals, really wanted anything to do with the machine gun even after the Kaiser demanded they have it.
But the major problem for Germany is the two front long war. Moltke considered that the long war was inevitable, which is why he didn't invade Holland for the Maastricht area's rail lines; he wanted to keep the Dutch neutral so that he could use them as a trading front with the world. Also, Moltke correctly realized that HIS plan (I am of the school that the Schlieffen plan really didn't exist other than as a funding ploy and the real plan was of Moltke's design) would not result in victory at 40 days. Really, he expected to hurt the French army badly enough that he could then transfer large numbers of troops East while mopping up the West.
Attacking Russia, while diplomatically logical, would only result in Germany's greatest fear: being stuck in Russia's vast wilderness with no strategic victories or plan to get out, while an undiminished and industrially intact France pounds at Germany's back door. He knew that the French would be the first to develop heavy artillery large enough to break through the Metz, Thionville, Strasbourg forts. With the vast land to hold down in Russia and with a weak ally (yes the German military realized that the Austro-Hungarians were not very useful as an ally), they will not have extra forces to use in the West, or at least not enough to hold back the French indefinitely while still trying to land a knock out blow against the Russians.
In hindsight we know that the Russians could not have politically lasted long with the Germans kicking in their front door, but the German military had their perspective changed when Russia made its rapid recovery after the Russo-Japanese war. Fearing that the Russians would be much tougher than they proved to be, the German high command assumed that they could not defeat Russia in an all out move like they could the French. They thought the French would capitulate quickly after losing an army or more.
It turns out they overestimated the Russians and underestimated the French, a situation to be reversed in WW2 based on experiences in WW1. The point is that even with the Kaiser more involved in getting extra funding for the army and pushing more technology on them, Moltke would be even more resistant to the Kaiser trying to butt his nose into military planning.
Historically even when the Kaiser ordered Moltke to change the thrust of the army East in early August 1914, he was ignored. Here that situation would be worse, what with Moltke resenting the Kaiser's input, but the general military situation better, as then Moltke can leave the Eastern Front comfortably in the hands of his 3 Eastern armies and keep all the West Heer in France. It would have interesting knock on effects for the conduct of the Marne campaign as there would be an extra two corps present for the battle, which was 2/3's the number of corps that were in the new 7th army that plugged the gap between the 1st and 2nd armies after that battle. That could very well mean that there is no need to pull back to the Aisne line, as the Marne river would be far enough to close the breech thanks to these corps, which could be reinforced by the historic 7th army. Also the Entente did not follow very hard on the heels of the retreating Germans, which means that they have breathing room to regroup and continue the offensive with reinforcements from the left wing...